Characterization of the hydrogen induced cold cracking. Cold cracking causes sharp edged, narrow crevices to form intermittently or completely throughout the weld and weld heataffected zone. Investigation of hydrogen embrittlement in 12cr2mo1rh steel. Cold cracking susceptibility of weld metal deposited by. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Hydrogen induced stress cracking of inconel 625 effect of production method, heat treatment and cold working. Investigation of hydrogen embrittlement in 12cr2mo1rh. The ygroove cracking test by submerged arc welding was employed to study the susceptibility of a lowcarbon highstrength steel to hydrogen induced cold cracking hicc. Hydrogen induced cold cracking studies on armour grade high. This was done by hydrogen precharging and stepwise loading in cortest proof rings, followed by an investigation of the fracture surfaces in a scanning. Therefore, it was aimed to identify and evaluate the effect of weld microstructure on cold cracking susceptibility of fcaw weld metals, and then to give a basic guideline for designing new welding consumables from the microstructural point of view. Hydrogeninduced cracking is also known as cold cracking, delayed cracking or underbead cracking. The crack behaviour was measured in terms of total crack length and distance from the fusion line.
Following world war ii, there was progressive development of hydrogeninduced cracking tests for a range of. The weldability of steel, with regard to hydrogen induced cold cracking, is inversely proportional to the hardenability of the steel, which measures the ease of forming martensite during heat treatment. The hardenability of steel depends on its chemical composition, with greater quantities of carbon and other. A specific objective was to investigate weld metal cold cracking susceptibility by. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. In order to increase the susceptibility to cracking, 2% and 5%h2 was deliberately added to the. The most typical forms of cracking are manufacturing related such as lack of fusion, cold welds and hook cracklike, operational driven fatigue cracks initiating at imperfections or dents and environmentally assisted stress corrosion cracking, hydrogen induced cracking and corrosion fatigue cracking. Welding of carbon and low alloy steels and hydrogen induced. Quantifying hydrogen induced cracking hic susceptibility. Cold cracking is also called hydrogeninduced cracking or simply hydrogen cracking because hydrogen trapped in the weld and heataffected zone is responsible for this type of cracking.
A metallographic analysis of these steels was performed before and after nace tm0284 standard testing. Nov 05, 2019 cold cracking is a welding discontinuity or welding defect, depending on the specification upon which the weld is being evaluated. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Hydrogen induced cracking hic is a phenomenon mainly associated with welds in low alloy steels. Defects hydrogen cracks in steels identification twi.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Hydrogeninduced cracking an overview sciencedirect topics. Hydrogen cracking may also be called cold cracking or delayed cracking. Unfortunately, the term hydrogeninduced cracking, usually abbreviated as hic, has been introduced to designate cracking sometimes encountered in pipelines or vessels as a result of hydrogen picked up in. Hic in welding cold cracking haz cracking moisture n org compounds r primary sources of h. Broadly speaking, cold cracking occurs in the haz as the result of residual stresses from the base material restraining the weld, along with the presence of diffusible hydrogen. Hydrogen cracking its causes, costs and future occurrence p h m hart weld metal hydrogen cracking in pipeline girth welds, proc. Inspection immediately after welding will never find it. The results showed that the heataffected zone haz has a higher susceptibility to hicc than the weld metal and that increasing heat input. Describes the characteristic features and principal causes of hydrogen cracks in. Sep 07, 2009 the methane molecules create a pressure which leads to embrittlement and even cracking of the metal.
Welding may cause increased hydrogen induced stress cracking susceptibility in the weld metal and in the haz adjacent to the fusion line. Controlled amounts of diffusible hydrogen were introduced into these weldments by utilizing the gas metal arc welding process with additions of hydrogen to the shielding gas. Dec 20, 2012 in the case of the lower hydrogen content, cold cracking susceptibility was very low in spite of the very high strength of the base steel regardless of chemical composition and rolling condition. This form of cracking is also commonly referred to as hydrogen. Also referred to as hydrogeninduced cold cracking, hydrogen cracking and delayed cracking, it requires the following during welding. Cold cracking is often referred to as hydrogeninduced andor heataffected zone haz cracking. Hydrogen assisted cracking cold cracking in the heat affected zones of welded cmn and low alloy steels and their weld metals is discussed with regard to hydrogen diffusion, residual stress, and. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Factors influencing hydrogen induced cracking welding.
The weldability of steel, with regard to hydrogeninduced cold cracking, is inversely proportional to the hardenability of the steel, which measures the ease of forming martensite during heat treatment. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Facing the practical difficulties in reducing the diffusible hydrogen content of fluxcontaining welding consumables like fluxcored are welding fcaw wires, the present study investigated the microstructural aspect to improve the hydrogeninduced cold crack hicc resistance of multipass weld metal of 600mpa strength. It is important to note that hydrogen induced cracking is not a weld defect, rather it is a condition that will create a crack. Cold cracking susceptibility of the weld metal made with a 16 %cr7 %ni wire was investigated using the y groove weld cracking test. Hydrogen induced cracking in flux cored electrode welds. The effects of heat input, underwater welding depths and composition of shielded gases on welds toughness. Weldability tests the first test methods for cold cracking emerged in the 1940s9, when the formation of martensite in the haz was the main cause of cracking. This wire was made on an experimental basis to be applied to 980 mpa grade steel without preheating. The relative susceptibilities to hydrogen induced cold cracking were evaluated for hy100, a steel presently in service in naval applications and for.
The relative susceptibility to hydrogen induced cracking of cold deformed aisi 4140 steel welds was investigated. The effect of grain size on the hisc susceptibility of inconel 625 samples charged with hydrogen. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. For further information contact manager repository services. Susceptibility to hydrogen induced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. Cold cracking, also called hydrogeninduced cracking. Pdf hydrogeninduced cold cracking in heataffected zone of low. Effect of arisen dislocation density and texture components during cold rolling and annealing treatments on hydrogen induced cracking susceptibility in pipeline steel. Hicc susceptibility of those two consumables was evaluated by gbop test and also by multipass weld metal cold cracking test. Characterisation of transverse cold cracking in weld metal of a high. Review of modeling and simulation of hydrogen induced cold. The relative susceptibilities to hydrogen induced cold cracking were evaluated for hy100, a steel presently in service in naval applications and for hsla100. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement.
From this investigation, the following conclusions are derived. The effects of chemical compositions, rolling conditions, and homogenization treatment on hydrogen induced cracking hic have been studied metallurgically using laboratory heats of chemical compositions corresponding to those of the center segregation zones in continuous cast slabs. This cited by count includes citations to the following articles in scholar. Ferriticaustenitic duplex stainless steels should be regarded as potentially susceptible to hydrogen induced stress cracking, independent of smys typically 400 to 550 mpa or specified maximum hardness. The susceptibility of carbon steel to hic can be mitigated by controlling the chemical composition in particular reducing the concentration of manganese sulphide inclusions in the steel.
Cold cracking susceptibility of austenitic and martensitic. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogen induced cold cracking in a low alloy steel. Welding of carbon and low alloy steels and hydrogen. Hydrogen induced stress cracking civilweb spreadsheets. The study of hydrogen embrittlement of 12cr2mo1rh steel by slow strain rate test with in situ hydrogen charging. Corrosion products were characterized by scanning electron microscopy and xray dispersive. Effect of microstructure on hydrogeninduced cracking of. Hydrogeninduced cracking hic tests were performed on fourteen types of x65 line pipe steels in various environments in which the hydrogen sulfide h 2 s partial pressures p h 2 s were in the range from 1. As a result of this study, it was demonstrated that microstructural modification with decreased proportion of grain boundary ferrite gf improved cold crack resistance of weld metal. Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater.
In low alloy steels, as the weld metal structure is more susceptible than the haz. Hydrogeninduced cold cracking in heataffected zone of. Weldments susceptible to cold cracking are required by the structural welding code aws d1. Cold cracking is a welding discontinuity or welding defect, depending on the specification upon which the weld is being evaluated. Hydrogen induced cold cracking in a low alloy steel american. Weldability of hsla steel and factors influencing susceptibility to cold cracking of welded joints. Cold cracking susceptibility of boron added highstrength. Cracking occurs due to a significant loss in ductility. It is also called hydrogen assisted cracking hac and delayed cracking since it does not occur right after welding, but a few hours or days after the weld has completely cooled down to ambient temperature. The martensitic microstructure of the hy100 undergoes wide variations in the heat affected zone during welding which strongly influence the resistance of that alloy to cold cracking. Understanding why your welds crack part i welding answers.
Rosen 15 types of pipeline cracks inspection solutions. Hydrogeninduced cold cracking in heataffected zone of low. Nov 14, 2014 the presence of hydrogen in the weld metal or haz may lead to a form of cracking known as hydrogen. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Corrosion products were characterized by scanning electron microscopy and xray dispersive energy spectrometry, which were. However, when the mixed shielding gas was used, cold cracking susceptibility increased due to an increase in the hydrogen content. Hydrogen induced cold cracking in weld metal is caused by the complex interaction of the diffusible hydrogen content, residual stress and susceptible. The tests are normally carried out according to nace tm0284. Abstract hydrogeninduced cracking hic has been studied phenomenologically. In this issue, the characteristic features and principal causes of hydrogen cracks are described.
A comparative study of hydrogeninduced cracking resistances. The welding was conducted at the condition of 260 a26 v23 cmmin with no preheating. The hydrogen embrittlement of 12cr2mo1rh steel at different strain rates were investigated after hydrogen precharging for 4 h in a 0. Debiez 12 used implant test a type of cold cracking tests to study the weldability of different high strength steels and concluded that the yield strength could be used to evaluate the susceptibility to hicc. The factors which contribute to hic are i presence of h2, ii high tensile stress, iii susceptible microstructures, iv temperatures which are between around 200 deg c and 100 deg c, and v time. Understanding hydrogen induced cold cracking in welds linkedin. Corrosionpedia what is hydrogeninduced cracking hic.
Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Understanding weld cracking, its causes, consequencesand. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Cold cracking is often referred to as hydrogen induced andor heataffected zone haz cracking. Also referred to as hydrogen induced cold cracking, hydrogen cracking and delayed cracking, it requires the following during welding. Following world war ii, there was progressive development of hydrogen induced cracking tests for a range of.
Hydrogen cracking its causes, costs and future occurrence. The following work has examined the effect of heat treatment, production method and cold working cw on the hydrogen induced stress cracking hisc susceptibility of inconel 625 uns n06625. Carbon is recognized as the alloying element with the greatest influence on the hardenability and cold cracking susceptibility of steels, but other alloying elements such as. The results showed that the heataffected zone haz has a higher susceptibility to hicc than the weld metal and that. Hydrogen induced stress cracking of inconel 625 effect of. The effects of wet welding conditions on diffusible hydrogen amount in the welds.
Pdf hydrogeninduced cold cracking in heataffected zone of. Hydrogen assisted cracking cold cracking in the heat affected zones of welded cmn and low alloy steels and their weld metals is discussed with regard to. Quantifying hydrogen induced cracking hic susceptibility of. Hydrogen induced stress cracking of inconel 625 effect. Factors influencing hydrogen induced cracking welding answers. Microstructural parameter controlling weld metal cold cracking. Hydrogen induced cold cracking studies on armour grade. A reduction in inclusions is achieved by lowering the sulphur content of the steel to below 0. The diffusible hydrogen contents of the different flux cored wires were evaluated by means of hydrogen evolution tests using glycerin as the collecting medium. Hydrogeninduced cracking susceptibility in highstrength. The effect of microstructure on hic is discussed for steels having two different levels of nonmetallic inclusions. Hydrogeninduced cracking hic is a far too common type of failure. The hydrogeninduced cracking hic susceptibility of weld met.
Pdf hydrogeninduced cold cracking in heataffected zone. Hydrogeninduced cracking is also known as cold cracking, delayed cracking or. Hydrogeninduced cracking susceptibility in highstrength weld metal a formula is proposed to estimate minimum preheat and interpass temperatures which help prevent hydrogeninduced cracking n. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Conditions of hydrogeninduced corrosion occurrence of x65. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments.
Hydrogen induced cracking susceptibility of highstrength. The morphology of hydrogen cracks was observed using an electron probe microscope. Zhang, kun fan, yicheng luo, xiaowei chen, xiaolang ban, chaolei zhao, heming and chen, yiqing 2019. It is always preferred to avoid martensitic structure in any form that is susceptible to hydrogen induced cold cracking leading to a catastrophic failure during welding. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Cold cracking susceptibility of weld metal deposited by gas. The most typical forms of cracking are manufacturing related such as lack of fusion, cold welds and hook cracklike, operational driven fatigue cracks initiating at imperfections or dents and environmentally assisted stress corrosion cracking, hydrogeninduced cracking and corrosion fatigue cracking. The presence of hydrogen in the weld metal or haz may lead to a form of cracking known as hydrogen. The ygroove cracking test by submerged arc welding was employed to study the susceptibility of a lowcarbon highstrength steel to hydrogeninduced cold cracking hicc. Although it depends on the application, cold cracking will usually lead to complete weld failure.